Chien-Ming Wang will start game 1 of the ALDS. I think that's the right call. He is the ace of this team. Here is the schedule (along with probable starters):

Game 1: Yankees at Indians, October 4 on TBS (Wang vs. C.C. Sabathia)
Game 2: Yankees at Indians, October 5 on TBS (Andy Pettitte vs. Fausto Carmona)
Game 3: Indians at Yankees, October 7 on TBS (Roger Clemens vs. Jake Westbrook)
*Game 4: Indians at Yankees, October 8 on TBS or TNT (Mike Mussina vs. Paul Byrd)
*Game 5: Yankees at Indians, October 10 on TBS (Wang vs. Sabathia)

* - if necessary. Times are yet to be announced.